Bronya Clare, Amal Sirwardana, Douglas R. MacFarlane's Ionic Liquids PDF

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Recently, synthesis of low-melting lanthanide-containing ionic liquids of the type [C4mim]x−3[Ln(NCS)x(H2O)y] (x = 6–8, y = 0–2, Ln = Y, La, Pr, Nd, Sm, Eu, Gd, Tb, Ho, Er, and Yb) have been reported [81]. 2 Functionalized Ionic Liquids During the last 8 years [82, 83], various types of functionalized ionic liquids (Fig. 13) expressly categorized as being “task-specific” ionic liquids have been designed and synthesized for specific purposes such as catalysis, organic synthesis, separation of specific materials, as well as for the construction of nanostructure materials and ion conductive materials, etc.

98] reported for the first time a functionalized ionic liquid with NH2 group, n-propylamine-3-butylimidazolium tetrafluoroborate 18, for capturing CO2 (Scheme 17). 2 Functional Group Covalently Tethered to the Anion Electroactive, functionalized ionic liquid, tetraalkylphosphonium polyoxometalates were synthesized by the substitution of sodium tungstate with tetaralkylphosphoniumbromide [(C6H13)3P(C14H29)]2W6O19 [99]. 3 Zwitterionic-Type Ohno et al. [100] reported that the synthesis of zwitterionic-type molten salts and their polymers (Scheme 18).

The [CRmim][ZnX2Y2] ionic liquid system (R = Me, Et, n-Bu, Benzyl; X = Y = Cl or Br or X = Cl, Y = Br) was synthesized by reacting ZnX2 with (1-R-3-methylimidazolium)Y [67]. The single crystal X-ray structural analysis and elemental analysis of [CRmim][ZnX2Y2] revealed that two imidazolium cations were paired with a dibromodichloro zincate dianion. In 1998, Dupont et al. [68] reported the synthesis of [C4mim]2[PdCl4] (Fig. 11). Solid IL-coordinated Pd2+ complex 13 was synthesized by the reaction of a nitrile functionalized ionic liquid with PdCl2 at room temperature.

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